Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin.
نویسندگان
چکیده
A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl(2) to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of pi-cation radical in the course of electrochemical oxidation.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 شماره
صفحات -
تاریخ انتشار 2008